Hydride Reduction of the Cations 5-C5H5)Fe>PF6, 5-C5H5)Ru>PF6, and 5-C5H5)Ru>PF6: Regioselectivity and Mechanism

DOI: 10.1039/c39810000341

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 341 - 342 (1981)

Update date:2022-08-03

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Authors:

Davies, Stephen G.

Felkin, Hugh

Fillebeen-Khan, Tauqir

Tadj, Fatemeh

Watts, Oliver

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Article abstract of DOI:10.1039/c39810000341

Reduction of the cation <(η⁵-C5H5)Fe(tripod)>PF6 with lithium aluminium hydride gives (η⁵-C5H5)FeH(tripod) via an S_N1 mechanism, involving prior dissociation of a phosphine ligand leading to direct attack of hydride on the metal, in contrast with the related ruthenium cations <(η⁵-C5H5)RuL3>PF6 (L3 = triphos or tripod) which give the cyclopentadiene complexes (η⁴-C5H6)RuL3 via exo-hydride attack on the cyclopentadienyl ligand .

Full text of DOI:10.1039/c39810000341

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