Journal of the Chemical Society. Chemical communications p. 341 - 342 (1981)
Update date:2022-08-03
Topics:
Davies, Stephen G.
Felkin, Hugh
Fillebeen-Khan, Tauqir
Tadj, Fatemeh
Watts, Oliver
Reduction of the cation <(η5-C5H5)Fe(tripod)>PF6 with lithium aluminium hydride gives (η5-C5H5)FeH(tripod) via an SN1 mechanism, involving prior dissociation of a phosphine ligand leading to direct attack of hydride on the metal, in contrast with the related ruthenium cations <(η5-C5H5)RuL3>PF6 (L3 = triphos or tripod) which give the cyclopentadiene complexes (η4-C5H6)RuL3 via exo-hydride attack on the cyclopentadienyl ligand
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