Synthesis of 1,2,3,4,6-Penta-O-acetyl-5-deoxy-5-C--α- and -β-D-glucopyranoses and Their Structural Analysis by 400-MHz Proton Nuclear Magnetic Resonance

DOI: 10.1021/jo00152a006

Source and publish data:

Journal of Organic Chemistry p. 435 - 440 (1983)

Update date:2022-08-05

Topics:

Authors:

Yamamoto, Hiroshi

Yamamoto, Keizo

Inokawa, Saburo

Yamashita, Mitsuji

Armour, Margaret-Ann

Nakashima, Tom T.

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Article abstract of DOI:10.1021/jo00152a006

Debenzylation of (5RS)-3,6-di-O-benzyl-5-deoxy-5-C--1,2-O-isopropylidene-α-D-xylo-hexofuranose (13) over 10 percent Pd/C afforded the tricyclic compound 14, which, on treatment with chlorotriphenylmethane in pyridine, provided a 1:

Full text of DOI:10.1021/jo00152a006

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