A NEW SYNTHESIS OF MACROCYCLIC KETO-LACTONES VIA RING EXPANSION OF 2-(3-HYDROXYPROPYL)-2-NITROCYCLOALKANONES

DOI: 10.1016/S0040-4039(00)87658-3

Source and publish data:

Tetrahedron Letters p. 3521 - 3524 (1982)

Update date:2022-08-04

Topics:

Authors:

Cookson, Richard C.

Ray, Partha S.

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Article abstract of DOI:10.1016/S0040-4039(00)87658-3

2-(3-Hydroxypropyl)-2-nitrocycloalkanones undergo base-catalysed isomerisation into nitro-lactones containing four more atoms in the ring, which can be smoothly converted to the corresponding keto-lactones.

Full text of DOI:10.1016/S0040-4039(00)87658-3

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