The Synthesis of Alkenes from Carbonyl Compounds and Carbanions α to Silicon. Stereoselective Synthesis of 1-Trimethylsilylbuta-1,3-dienes

DOI: 10.1039/c39820000969

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 969 - 970 (1982)

Update date:2022-08-03

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Authors:

Chan, Tak-Hang

Li, Ji-Sheng

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Article abstract of DOI:10.1039/c39820000969

Reactions of aldehydes with the 1,3-bis(trimethylsilyl)propenyl anion in the presence of magnesium bromide or trimethyl borate give stereoselectively the alcohols (2) which can be transformed stereospecifically to either (1E,3E)- or (1E,3Z)-1-trimethylsilylbuta-1,3-dienes.

Full text of DOI:10.1039/c39820000969

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