A total synthesis of a new class of biazine thioglycosides

Article abstract of DOI:10.1081/CAR-200045262

A new method for the synthesis of bipyridinyl S -glycosides 11 and 12 has provided the title compounds in a higher yield. Application of a one-pot glycosylation methodology resulted in an efficient, high-yield synthesis of biazine S -glycosides 17-20 An X-ray diffraction analysis of 11 disclosed the conformation of this glycoside as the S -glycoside and not the corresponding N -form. Copyright