Bulletin of the Chemical Society of Japan p. 3939 - 3940 (1982)
Update date:2022-08-05
Topics:
Tada, Masaru
Akinaga, Shiro
Okabe, Masami
Photolysis of (methoxycarbonyl-2-phenylpropyl)cobaloxime (1) gives two phenyl-migrated products, methyl 2-methylene-3-phenylpropanoate and methyl trans-2-methyl-3-phenylpropenoate, and a hydrogen abstracted product, methyl 2-methyl-2-phenylpropanoate.The alkoxycarbonyl groups do not migrate in the photolysis of either 1 or <2,2-bis(ethoxycarbonyl)propyl>cobaloxime.
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