Journal of the Chemical Society. Chemical communications p. 1232 - 1233 (1982)
Update date:2022-07-29
Topics:
Nishiyama, Hisao
Kitajima, Toshio
Yamamoto, Akiko
Itoh, Kenji
2-Hydroxy-3-trimethylsilylpropyl selenides, readily prepared by the reaction of α-phenylselenoaldehydes and trimethylsilylmethyl-lithium, are transformed into primary allylic selenides and β-trimethylsilylpropanals by acid-catalysed dehydroxysilylation accompanied by a phenylseleno-shift, and by silver-induced rearrangement of the trimethylsilylmethyl group, respectively.
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