Journal of the American Chemical Society p. 2985 - 2989 (1986)
Update date:2022-08-05
Topics:
Vedejs, Edwin
Perry, David A.
Wilde, Richard G.
The title compound is the first aliphatic thioaldehyde to be observed under odinary laboratory conditions.Its spectral data and chemical characterization are described, including 2+3 cycloadditions with nitronate ester 6, 2+4 cycloaddition with reactive dienes, thiophilic addition with phenyllithium, carbophilic addition with butyllithium, conversion to episulfide 15 by the Wittig reagent, and oxidation to sulfine 17 with MCPBA.Independent generation of thiopivaldehyde from tert-butyllithium + ethyl thionoformate followed by heating 9 in xylene or by cycloreversion of 2-tert-butyl-1,2-dithiolane with butyllithium are also described.
View MoreContact:86-25-84683399
Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Liaoyang Xinyou Chemical Products Co.,Ltd.
Contact:+86-419-5165433 13604191870
Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Shanghai Egoal Chemical Co.,Ltd
Contact:+86-21-50333091
Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Chemsigma International Co.,Ltd.
website:http://www.chemsigma.com
Contact:86-025-58748998
Address:Rm.705, 15th Building,Rd.Xinke II
Doi:10.1002/ejoc.201800629
(2018)Doi:10.1039/jr9640004730
(1964)Doi:10.3987/COM-04-10265
(2005)Doi:10.1021/jo00156a021
(1983)Doi:10.1016/j.bmc.2015.07.059
(2015)Doi:10.1039/b415810e
(2005)
