Journal of Organic Chemistry p. 9854 - 9859 (2014)
Update date:2022-08-05
Topics:
Okamoto, Noriko
Sueda, Takuya
Yanada, Reiko
Bi(OTf)3-catalyzed Meyer-Schuster rearrangement of electron-rich propargyl alcohols, followed by 1,4-addition of the resulting vinyl ketone, proceeded smoothly though Meyer-Schuster rearrangement of primary propargyl alcohols is rare. This tandem reaction can be extended to an intramolecular version, featuring a one-pot dihydroquinolone synthesis. (Chemical Equation Presented).
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