Journal of Organic Chemistry p. 1144 - 1146 (1983)
Update date:2022-08-03
Topics:
Seyferth, Dietmar
Weinstein, Robert M.
Wang, Wei-Liang
The in situ generation of n-C4H9C(O)Li by the reaction of n-C4H9Li with CO at -110 deg C in the presence of ketones gives good (50-90percent) yields of α-hydroxy ketones.When the n-C4H9C(O)Li reaction is carried out in the presence of esters, good (65-80percent) yields of α-diketones are obtained, thus demonstrating that RC(O)Li can be reagents of practical utility.Similar reactions were observed with sec-C4H9Li and tert-C4H9Li.
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