Exploiting phosphonate chemistry in metal-mediated dearomatization: Stereoselective construction of functionalized spirolactams from arene ruthenium complexes

DOI: 10.1021/ja058342y

Source and publish data:

Journal of the American Chemical Society p. 3498 - 3499 (2006)

Update date:2022-08-04

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Authors:

Pigge, F. Christopher

Coniglio, John J.

Dalvi, Rashmi

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Article abstract of DOI:10.1021/ja058342y

Arene ruthenium complexes possessing β-amido phosphonate side chains participate in intramolecular spirocyclization reactions to deliver stable cyclohexadienyl ruthenium adducts. Spirocyclization is accomplished via a tandem two-step sequence that involve

Full text of DOI:10.1021/ja058342y

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