Bulletin of the Chemical Society of Japan p. 192 - 198 (1983)
Update date:2022-08-05
Topics:
Shimizu, Iwao
Kamei, Yoshio
Tezuka, Takeshi
Izumi, Taeko
Kasahara, Akira
Some ferrocenophanes, in which the two cyclopentadienyl rings are linked by biphenyl rings, have been synthesized via intramolecular reductive coupling of the corresponding formyl compounds with a low-valent titanium reagent.The structures of these cyclophane compounds were determined by IR, NMR, and UV spectra analyses.Transannular ?-electronic interactions between the two biphenyl rings were examined on the basis of electronic spectra.
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