Bulletin of the Chemical Society of Japan p. 630 - 632 (1989)
Update date:2022-07-30
Topics:
Song, Chunshan
Ono, Tomohiro
Nomura, Masakatsu
The MoCl3- and NiCl2-LiCl-KCl salts, which are effective coal liquefaction catalysts, promoted the hydrogenation of anthracene (at 400 deg C for 1 h with 9.8 MPa H2) and afforded tetrahydro- and octahydro- as well as dihydroanthracene as major products.However, these catalysts did not remarkably enhance the ring-opening cracking reactions.A comparative examination suggested that the addition of LiCl-KCl to MoCl3 and NiCl2 suppressed their cracking ability and improved their hydrogenation selectivity.
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