THE STEREOSELECTIVE SYNTHESIS OF 2,3-CIS-DIHYDROXY-γ-BUTYROLACTONES BY THE OXIDATION OF γ-BUTENOLIDES WITH KMnO4-CROWN ETHER

DOI: 10.1246/cl.1983.173

Source and publish data:

Chemistry Letters p. 173 - 174 (1983)

Update date:2022-08-03

Topics:

Authors:

Mukaiyama, Teruaki

Tabusa, Fujio

Suzuki, Keisuke

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Article abstract of DOI:10.1246/cl.1983.173

Oxidation of γ-butenolides was effected by KMnO4-crown ether to afford the corresponding 2,3-cis-dihydroxy-γ-butyrolactones in high yields.High stereoselectivity was observed in cases when bulky substituents were introduced at the γ-position of the buteno

Full text of DOI:10.1246/cl.1983.173

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