Journal of the American Chemical Society p. 3886 - 3893 (1983)
Update date:2022-08-04
Topics: Infrared spectra
Kafafi
Hauge
Billups
Margrave
Lithium atoms react spontaneously with carbon dioxide to form Li** plus CO//2** minus and Li//2**2** plus CO//2**2** minus in inert gas matrices. Reaction of Li and CO//2 in an argon matrix leads also to the formation of Li** plus C//2O//4** minus . Two geometrical isomers of Li** plus CO//2** minus have been isolated in solid argon. One has a ring structure in which the metal interacts symmetrically with the two oxygen atoms, while in the second isomer the lithium atom is bonded to only one of the two oxygens.
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