Evidence for radical cations in linked mechanisms of N,N-Dialkyl aromatic amine nitration and nitrosative dealkylation

DOI: 10.1021/ja9732744

Source and publish data:

Journal of the American Chemical Society p. 5193 - 5202 (1998)

Update date:2022-08-03

Topics:

Authors:

Loeppky, Richard N.

Singh, Sukhjeet P.

Elomari, Saleh

Hastings, Riley

Theiss, Thomas E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja9732744

N,N,-Dialkyl aromatic amines react rapidly with nitrous acid to competitively produced a nitrosamine and a nitro compound. The mechanism of nitro compound formation involves a reaction of an amine radical cation with NO₂, while the nitrosamine

Full text of DOI:10.1021/ja9732744

Products guided by the article

Product name:4-CO₂Et-C₆H₄N(CD₃)2

Cas No:853783-69-4

R&D Labs maybe for 853783-69-4

Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA

Relevant to this article

Reversal of the regioselectivity of anthrapyrazole formation. A new synthesis of Losoxantrone (DUP941)

Doi:10.1016/S0040-4039(00)73069-3
(1994)
CO bond activation and subsequent decarbonylation of ester promoted by Fe(PMe₃)₄

Doi:10.1016/j.inoche.2013.12.026
(2014)
A synthesis of the platelet aggregation inhibitor xemilofiban from L- aspartic acid. Confirmation of the absolute configuration

Doi:10.1016/S0040-4039(98)00602-9
(1998)
Studies on β-lactam antibiotics - Iv: An improved synthesis of 3-(isothiazolylthiomethyl)cephalosporins and its application to new derivatives

Doi:10.7164/antibiotics.47.477
(1994)
Synthesis and Structure - Activity Relationships of New Antitumor Taxoids. Effects of Cyclohexyl Substitution at the C-3'-and/or C-2 of Taxotere (Docetaxel)

Doi:10.1021/jm00042a013
(1994)
Ultrahigh-field NMR spectroscopy of quadrupolar transition metals: ⁵⁵Mn NMR of several solid manganese carbonyls

Doi:10.1021/ic0608445
(2006)

Article Doi