Journal of the American Chemical Society p. 3563 - 3567 (1983)
Update date:2022-07-29
Topics: Ligand Carbene Nucleophilic substitution Cyclopentadiene Ylides Reaction Mechanism Cycloaddition Spectroscopic Analysis Electrophilic addition Resonance stabilization Trifluoromethyl group (–CF?)
Janulis, Eugene P.
Arduengo, Anthony J.
The synthesis of dizotetrakis(trifluoromethyl)cyclopentadiene (1) is described.This stable perfluorinated diazo compound undergoes a photochemical loss of nitrogen to yield a reactive intermediate which reacts with a variety of elements bearing lone pairs
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