Tetrahedron p. 2805 - 2810 (1982)
Update date:2022-08-05
Topics:
Glanzmann, Michael
Karalai, Chatchanok
Ostersehlt, Bernd
Schoen, Uwe
Frese, Christiane
Winterfeldt, Ekkehard
The spirocyclization of straight-chain triketo-intermediates, similar to possible biogenetic precursors of histrionicotoxin, is shown to be stereoselective, generating the non-natural configuration at C-2.Aiming at an sp2-center in this positio
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