
Helvetica Chimica Acta p. 2563 - 2569 (1982)
Update date:2022-08-04
Topics:
Fink, Margot
Gaier, Hans
Gerlach, Hans
Methyl 2,3-alkadienoates 2 are shown to react at 80 deg C with 1,1-dimethoxy-3-trimethylsilyloxy-1,3-butadiene (1) to give the adducts 3 in good yields.Rearrangement of 3, catalyzed by p-toluenesulfonic acid or by sodium methoxide, affords the 6-substitut
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