Restricted Rotation Involving the Tetrahedral Carbon. XLV. Appearance of a Maximum in the Rotational Barriers of 9-(1,1-Dimethyl-2-phenylethyl)triptycenes at a Medium-sized peri-Substituent

DOI: 10.1246/bcsj.56.306

Source and publish data:

Bulletin of the Chemical Society of Japan p. 306 - 313 (1983)

Update date:2022-08-03

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Authors:

Yamamoto, Gaku

Suzuki, Masahiko

Oki, Michinori

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Article abstract of DOI:10.1246/bcsj.56.306

Rotational isomers of seven peri-substituted 9-(1,1-dimethyl-2-phenylethyl)triptycene derivatives were stereoselectively synthesized and classical kinetics on rotational isomerization were studied.While compounds with relatively small peri-substituents (F

Full text of DOI:10.1246/bcsj.56.306

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