Angewandte Chemie - International Edition p. 9939 - 9943 (2019)
Update date:2022-09-26
Topics:
Hilpert, Lukas J.
Breit, Bernhard
A rare case of a parallel kinetic resolution of racemic 1,3-disubstituted allenes by means of a rhodium-catalyzed addition to 1,3-diketones furnishing enantiopure allylic 1,3-diketones is described. Mechanistic experiments demonstrate that the different allene enantiomers react in parallel to either the diastereomeric E- or Z-allylic 1,3-diketones with the same absolute configuration of the newly formed stereogenic center. A broad substrate scope demonstrates the synthetic utility of this new method.
View MoreYueyang Hudex Pharmaceuticals Ltd.
Contact:0730-8748800
Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone
Lanzhou huibang biological chemical technology Co., LTD
Contact:0931-7843964
Address:NO.2011,Yannan Road,Chengguan,
Shenzhen Hongyuan Import & Export Co., Ltd.
Contact:0755-26407171
Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.
Jiaozuo Zhongwen Trading Coporation Limited
Contact:--
Address:East Renmin Road
NingBO Hong Xiang Biochem.Co.Ltd
website:http://www.hxbiochem.com
Contact:0574-66003444
Address:Ning Bo Bei Lun
Doi:10.1055/s-2005-865217
(2005)Doi:10.1016/j.tetasy.2005.04.004
(2005)Doi:10.1002/ardp.19723050608
(1972)Doi:10.1016/0008-6215(83)88156-7
(1983)Doi:10.1039/P29830000175
(1983)Doi:10.1039/b503981a
(2005)
