Pentacyclic Systems for Indole Alkaloids. Formation of the C11-C12 Bond. Two Synthesis of (+/-)-Aspidospermine

DOI: 10.1021/ja00352a038

Source and publish data:

Journal of the American Chemical Society p. 4750 - 4757 (1983)

Update date:2022-08-03

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Authors:

Gallagher, Timothy

Magnus, Philip

Huufman, John C.

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Article abstract of DOI:10.1021/ja00352a038

The tetracyclic amide 10 was converted through an intramolecular Pummerer reaction into the petacyclic amide11, having the basic framework of the Aspidosperma alkaloids.Application of this methodology to the synthesis of (+/-)-aspidosper

Full text of DOI:10.1021/ja00352a038

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