Pentacyclic Systems for Indole Alkaloids. Formation of the C11-C12 Bond. Two Synthesis of (+/-)-Aspidospermine

DOI: 10.1021/ja00352a038

Source and publish data:

Journal of the American Chemical Society p. 4750 - 4757 (1983)

Update date:2022-08-03

Topics:

Authors:

Gallagher, Timothy

Magnus, Philip

Huufman, John C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00352a038

The tetracyclic amide 10 was converted through an intramolecular Pummerer reaction into the petacyclic amide11, having the basic framework of the Aspidosperma alkaloids.Application of this methodology to the synthesis of (+/-)-aspidosper

Full text of DOI:10.1021/ja00352a038

Products guided by the article

Product name:2-(phenylsulfinyl)acetyl-cis-2,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1H-pyrido<3,2-c>carbazole

Cas No:85924-09-0

R&D Labs maybe for 85924-09-0

Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou
Xi'an Herbland Tech Inc.

Contact:+86-29-88710656

Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China

Relevant to this article

Stereocontrolled synthesis of the oxabicyclo[2.2.1]heptane segment of solanoeclepin A

Doi:10.1055/s-2005-865291
(2005)
Doi:10.1021/ja01626a070
(1955)
Doi:10.1007/BF01522232
(1933)
Reaction of Schiff bases with trichloroacetyl chloride in the presence of triphenylphosphine

Doi:10.1248/cpb.24.1935
(1976)
Formation and Reactions of 1-Phenyl-2-propanone Dianion and Related Systems with Electrophilic Reagents

Doi:10.1021/jo00166a004
(1983)
Synthesis and characterization of 1,3-dihydro-benzo[b][1,4]diazepin-2-one derivatives: Part 4. in vivo active potent and selective non-competitive metabotropic glutamate receptor 2/3 antagonists

Doi:10.1016/j.bmcl.2010.09.125
(2010)

Article Doi