Effective Synthesis of 2-propionic Acid via Hydromagnesation Reaction with Nickel or Titanium Catalysts

DOI: 10.1246/bcsj.59.1656

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1656 - 1658 (1986)

Update date:2022-07-29

Topics:

Authors:

Amano, Takehiro

Ota, Tomomi

Yoshikawa, Kensei

Sano, Tatsuhiko

Ohuchi, Yutaka

et al. et al.

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Article abstract of DOI:10.1246/bcsj.59.1656

2-<4-(3-methyl-2-butenyl)phenyl>propionic acid was synthesized in 82percent yield via nickel(II) chloride or dichlorobis<η⁵-cyclopentadienyl>titanium-catalyzed hydromagnesation of 1-(3-methyl-2-butenyl)-4-vinylbenzene obtained in ca. 63-68percent yield by the coupling reaction of 4-(3-methyl-2-butenyl)phenylmagnesium chloride with vinyl chloride.

Full text of DOI:10.1246/bcsj.59.1656

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