Tetrahedron Letters p. 97 - 100 (1983)
Update date:2022-08-05
Topics:
Barker, Philip J.
Beckwith, Athelstan L. J.
Fung, Y.
p-Toluenethiol/oxygen co-oxidation of 5-methylhepta-1,3,6-triene (1) gives inter alia only one (6a) of four possible diastereoisomeric dioxolanes, and threo- and erythro-isomers of the 1,4-addition product (10, 11).The variation in relative yields with thiol concentration indicates that coupling of the allylic radical (2) with oxygen is reversible.
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(2005)Doi:10.1021/ol051234w
(2005)Doi:10.1021/ja01158a509
(1950)Doi:10.1016/j.tet.2005.04.022
(2005)Doi:10.1016/j.bmcl.2007.04.065
(2007)Doi:10.1016/S0020-1693(00)83666-X
(1983)
