PO-Activated Olefination and Conversion of Aldehydes and Ketones to Higher Amines; II. Synthesis of Arylethylamines

DOI: 10.1055/s-1987-27902

Source and publish data:

Synthesis p. 245 - 249 (1987)

Update date:2022-08-03

Topics:

Authors:

Heymes, A.

Chekroun, I.

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Article abstract of DOI:10.1055/s-1987-27902

The transformation of arylcarboxaldehydes and/or - ketones 2 by three different routes into arylethylamines 3 and/or 4 is reported.According to the first route, the intermediate iminophosphonates 9 react through a classical PO-activated olefination.The second and the third involve the rearrangement of the iminophosphonates 9 into the vinylphosphoramidates 12.

Full text of DOI:10.1055/s-1987-27902

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