Synthesis of a Chiral [2]Rotaxane: Induction of a Helical Structure through Double Threading

DOI: 10.1021/acs.orglett.8b01727

Source and publish data:

Organic Letters p. 4745 - 4748 (2018)

Update date:2022-07-30

Topics:

Authors:

Tsukamoto, Toshihiro

Sasahara, Ryota

Muranaka, Atsuya

Miura, Yuzuki

Suzuki, Yu

Kimura, Masaki

Miyagawa, Shinobu

Kawasaki, Tsuneomi

Kobayashi, Nagao

Uchiyama, Masanobu

Tokunaga, Yuji

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Article abstract of DOI:10.1021/acs.orglett.8b01727

A helically chiral [2]rotaxane featuring two ammonium ion recognition sites in the dumbbell-like component and a calix-bis-crown ether as the macrocyclic component was synthesized, but with no chirality in either individual component. The enantiomeric nat

Full text of DOI:10.1021/acs.orglett.8b01727

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Product name:2-(2-(4-[2-(1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)ETHOXY]PHENOXY)ETHYL)-1H-ISOINDOLE-1,3(2H)-DIONE

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