Tetrahedron p. 10087 - 10092 (1992)
Update date:2022-08-04
Topics:
Subbaraju
Urbanczyk-Lipkowska
Newaz
Manhas
Bose
During the oxidation of conjugated enones to α-acyloxyoxiranes by m-chloroperbenzoic acid, the preferred sequence is epoxidation followed by Baeyer-Villiger oxidation. Rearrangement of acyloxyoxiranes to α-acyloxyketones, in situ, was observed. The α-keto
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