ISOCYANIDE AND HETEROALLENE BRIDGED METAL COMPLEXES. VI. REACTIONS OF CARBON DISULFIDE IRON, PALLADIUM AND PLATINUM COMPLEXES WITH ELECTROPHILES. EVIDENCE FOR A η2-CS2H LIGAND

DOI: 10.1016/S0022-328X(00)98656-X

Source and publish data:

Journal of Organometallic Chemistry p. 105 - 114 (1983)

Update date:2022-08-03

Topics:

Authors:

Stolzenberg, H.

Fehlhammer, W. P.

Dixneuf, P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)98656-X

S-Alkylation of 2-CS2)(PPh3)> (M=Pd, Pt) is achieved using stoichiometric amounts of the 'hard' alkylating agents and CF3SO2OMe, while MeI or 1,2-diiodoethane give <(Ph3P)2(I)Pt(μ-CS2)Pt(PPh3)2>I and <(Ph3P)2(I)Pt(μ-CS2)Pt(I)PPh3>, respectively.Protonation of 2-CS2)(CO)2L2> (L=PMe2Ph, PPh3) affords extremely labile complexes containing the novel η²-CS2H ligand.The first cationic η²:η¹-CS2 bridged dinuclear complexes (L=PMe2Ph, PPh3) serve as models for the assumed intermediate in the formation of metallodithiocarboxylato(S,S') metal compounds.

Full text of DOI:10.1016/S0022-328X(00)98656-X

Products guided by the article

Product name:[(PPh3)2(I)Pt(μ-CS2)Pt(PPh3)I]

Cas No:86176-21-8

R&D Labs maybe for 86176-21-8

Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing
TIC Gums, Inc.

Contact:410-273-7300; 800-221-3953

Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Bis(triarylmethylium)-mediated diaryl ether synthesis: Oxidative arylation of phenols with N,N-dialkyl-4-phenylthioanilines

Doi:10.1021/ja051839n
(2005)
Synthetic-method-dependent magnetic relaxation in a cobalt(II) phosphonate chain compound

Doi:10.1021/ic5021737
(2014)
Ti-catalyzed reactions of hindered isocyanates with alcohols

Doi:10.1021/jo050712d
(2005)
SYNTHESIS OF STABLE FURAN PROSTACYCLIN ANALOGS

Doi:10.1016/S0040-4039(00)81323-4
(1983)
Synthesis, dual fluorescence, and fluoroionophoric behavior of dipyridylaminomethylstilbenes

Doi:10.1021/jo0509049
(2005)
Enthalpy—entropy compensation upon metal ion coordination with porphyrins: generalization for the free bases and doubly deprotonated macrocycles

Doi:10.1007/s11172-020-2868-6
(2020)

Article Doi