Tetrahedron Letters p. 807 - 808 (1983)
Update date:2022-07-29
Topics:
Hayashi, Tamio
Okamoto, Yasuo
Kumada, Makoto
An optically active propargylsilane, (S)-1,3-diphenyl-3-trimethylsilylpropyne, prepared by palladium-catalyzed asymmetric Grignard cross-coupling, was found to react with t-butyl chloride in the presence of titanium chloride with anti stereochemistry to give (S)-1,3-diphenyl-4,4-dimethyl-1,2-pentadiene.
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Doi:10.1002/jhet.5570200104
(1983)Doi:10.1002/chem.201402286
(2014)Doi:10.1055/s-1996-4151
(1996)Doi:10.1124/dmd.111.040865
(2011)Doi:10.1021/jacs.1c01073
(2021)Doi:10.1002/omr.1270210404
(1983)