Stereochemistry of the Platinum Catalyzed Hydroformylation of Olefins

DOI: 10.1002/hlca.19810640620

Source and publish data:

Helvetica Chimica Acta p. 1865 - 1869 (1981)

Update date:2022-08-04

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Authors:

Haelg, Paul

Consiglio, Giambattista

Pino, Piero

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Article abstract of DOI:10.1002/hlca.19810640620

The deuterioformylation of (Z)- or (E)-2-butene catalyzed by Pt(SnCl3)Cl gives predominantly erythro- or threo-1,3-<(2)H>2-2-methylbutanal respectively.Hence, hydroformylation by this catalytic system must take place with cis-stereochemistry.

Full text of DOI:10.1002/hlca.19810640620

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