Journal of the Chemical Society, Dalton Transactions p. 665 - 670 (1983)
Update date:2022-08-04
Topics:
Cardin, Christine J.
Cardin, David J.
Norton, Reginald J.
Parge, Hans E.
Muir, Kenneth W.
Reaction of tin(II) chloride with Li(CPh=CPh2) at -78 deg C in diethyl ether-hexane-tetrahydrofuran affords a deep red solution whose colour fades on warming, and which we believe contains the (unstable) first dialkenyltin(II) species.The latter survives long enough at low temperatures to undergo intermolecular oxidative addition, and one such adduct leads ultimately to the formation of Sn(CPh=CPh2)3Bun, which has been fully characterised including a crystal and molecular structure study.The mechanism of formation of the final product has been examined and results are reported.
Jining tiansheng chemical co.,ltd.
Contact:+86-537-5158722
Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.
Contact:+86-417-2927806
Address:yingkou
Huzhou City Linghu Xinwang Chemical Co.,Ltd.
Contact:86-572-3948695/3945236
Address:huzhou
GUANGZHOU MEDCAN PHARMATECH LTD
website:http://www.gzmedcan.com
Contact:+86-20-82519649
Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Wuhan Kemi-Works Chemical Co., Ltd
website:http://www.kemiworks.com
Contact:86-27-85736489
Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Doi:10.1016/j.bmc.2006.05.070
(2006)Doi:10.1039/c6cc07365d
(2016)Doi:10.1135/cccc20000524
(2000)Doi:10.1081/SCC-100107018
(2001)Doi:10.1016/S0040-4039(00)81605-6
(1983)Doi:10.1016/j.bmcl.2009.11.060
(2010)
