Synthesis and Reactions of the Heterobimetallic Complex

DOI: 10.1039/DT9830000889

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 889 - 896 (1983)

Update date:2022-08-04

Topics:

Authors:

Pringle, Paul G.

Shaw, Bernard L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830000889

New methods of preparing (1b) (dppm = Ph2PCH2PPh2) are described, such as reduction of with zinc dust, formic acid, or hydrazine.Treatment of 3-allyl)2> with an excess of dppm gives pure (1b) readily, albeit in only 45 percent yield. <(η³-C3H5)ClPd(μ-dppm)PdCl(η³-C3H5)> is also described.The best route to (1b) is to treat and dppm with giving yields of 80-90 percent.Similar treatment of and dppm with t)2> gives (1a), often contaminated, however, with ca. 10 percent of .Treatment of dppm and with t)2> gives the previously unknown heterobimetallic complex (1c) in excellent yield (83-92 percent) and purity.The corresponding dibromide, di-iodide, and dithiocyanate were prepared from (1c) by metathesis.Complex (1c) readily reacts with some small molecules, SO2, CO, MeO2CCCCO2Me or CS2, to give 'A-frames' , , , and respectively.The addition of SO2, CO, or CS2 is reversible and SO2 promotes or catalyses the displacement of CO.Hydrogen-1, 31P-<1H>, and 195Pt n.m.r. data are given and discussed as are some i.r. data.

Full text of DOI:10.1039/DT9830000889

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Pd2Cl2(η3-C3H5)2(μ-dppm)]

Cas No:86361-86-6

R&D Labs maybe for 86361-86-6

Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
shanghai jiuling chemical co.,ltd.

Contact:+86-21-50387295

Address:Zaozhuang Road, Pudong, Shanghai City. China
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
puyang hongda shengdao new material co.,ltd.

Contact:+86-393- 4896278

Address:No.29 East Zhongyuan Road

Relevant to this article

Ruthenium-promoted Z-selective head-to-head dimerization of terminal alkynes in organic and aqueous media

Doi:10.1021/om050355x
(2005)
Cycloisomerization of 1,6-enynes: Asymmetric multistep preparation of a hydrindane framework in water with polymeric catalysts

Doi:10.1021/ol047700j
(2005)
Thione complexes of Rh(I): A first comparison with the bonding and catalytic activity of related carbene and imine compounds

Doi:10.1039/b414040k
(2005)
Doi:10.1021/ja00197a074
(1989)
Exploring quercetin and luteolin derivatives as antiangiogenic agents

Doi:10.1016/j.ejmech.2015.04.056
(2015)
AKTIVIERUNG VON KOHLENDIOXID AN UEBERGANGSMETALLZENTREN: NICKEL(II)-HETEROCYCLEN AUS KOHLENDIOXID UND AZAOLEFINEN AM ELEKTRONENREICHEN NICKEL(0)-KOMPLEXRUMPF

Doi:10.1016/S0022-328X(00)86795-9
(1982)

Article Doi