Organometallics p. 1062 - 1064 (1983)
Update date:2022-09-26
Topics:
Beanan, Lawrence R.
Rahman, Zuraldah Abdul
Keister, Jerome B.
The clusters H3Ru3(μ3-CX)(CO)9 (X = OMe, Me, Ph) react with alkynes C2R2 to form the corresponding alkene C2H2R2 and HRu3(μ3-η3-CXCRCR)(CO)9. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu3(μ3-η3-C(OMe)CRCR)(CO)9 yields the corresponding H3Ru3(μ3-CCHRCH2R)(CO) 9.
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Doi:10.1039/c4nj02372b
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(2005)
