Efficient construction of the oxatricyclo[6.3.1.00,0]dodecane core of komaroviquinone using a cyclization/cycloaddition cascade of a rhodium carbenoid intermediate

DOI: 10.1021/ol0513589

Source and publish data:

Organic Letters p. 3725 - 3727 (2005)

Update date:2022-08-05

Topics:

Authors:

Padwa, Albert

Boonsombat, Jutatip

Rashatasakhon, Paitoon

Willis, Jerremey

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Article abstract of DOI:10.1021/ol0513589

(Chemical Equation Presented) The rhodium(II)-catalyzed cyclization/cycloaddition cascade of a o-carbomethoxyaryl diazo dione is described as a potential route to the oxatricyclo[6.3.1.0^0.0]dodecane substructure of the icetexane diterpene komar

Full text of DOI:10.1021/ol0513589

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