ASYMMETRIC SYNTHESIS OF PROTECTED α-HYDROXYALDEHYDES FROM ACYL CHLORIDES USING p-TOLYL p-TOLYLTHIOMETHYL SULFOXIDE AS CHIRAL CARBONYL SYNTHON

DOI: 10.1016/S0040-4039(00)81536-1

Source and publish data:

Tetrahedron Letters p. 817 - 818 (1983)

Update date:2022-07-30

Topics:

Authors:

Guanti, Giuseppe

Narisano, Enrica

Banfi, Luca

Scolastico, Carlo

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Article abstract of DOI:10.1016/S0040-4039(00)81536-1

Carbonyl protected α-hydroxyaldehydes 3 were obtained in high diastereomeric purity through LiAlH₄ reduction of corresponding β-sulfoxides 2 prepared via acylation of p-tolyl p-tolylthiomethyl sulfoxide 1.

Full text of DOI:10.1016/S0040-4039(00)81536-1

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