1,5-BIS(TRIMETHYLSILOXY)-1,5-DIMETHOXY-1, 4-PENTADIENES PRECURSORS FOR THE SYNTHESIS OF CYCLOPROPANES AND CYCLOBUTANES

DOI: 10.1016/S0040-4020(01)88582-3

Source and publish data:

Tetrahedron p. 847 - 854 (1983)

Update date:2022-08-04

Topics:

Authors:

Wallace, I. H. M.

Chan, T. H.

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Article abstract of DOI:10.1016/S0040-4020(01)88582-3

1,5-Bis(trimethylsiloxy)-1,5-dimethoxy-1,4-pentadienes (7) can be prepared in good yield by silylation of the dianions of dimethyl glutarates (8).On treatment with titanium tetrachloride, 7 cyclise stereoselectively to dimethyl trans-cyclopropane-1,2-dica

Full text of DOI:10.1016/S0040-4020(01)88582-3

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Product name:2-(Methoxy-phenyl-methyl)-3-methyl-pentanedioic acid dimethyl ester

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