45. Total Synthesis of (+/-)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage

DOI: 10.1002/hlca.19830660213

Source and publish data:

Helvetica Chimica Acta p. 522 - 533 (1983)

Update date:2022-09-26

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Authors:

Oppolzer, Wolfgang

Zutterman, Freddy

Baettig, Kurt

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Article abstract of DOI:10.1002/hlca.19830660213

(+/-)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps.The key steps (Scheme 6) are the regio- and stereoselective photo<2+2>addition 7 -> 6 and the reductive fragmentation 6 -> 5.

Full text of DOI:10.1002/hlca.19830660213

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