45. Total Synthesis of (+/-)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage

DOI: 10.1002/hlca.19830660213

Source and publish data:

Helvetica Chimica Acta p. 522 - 533 (1983)

Update date:2022-09-26

Topics:

Authors:

Oppolzer, Wolfgang

Zutterman, Freddy

Baettig, Kurt

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19830660213

(+/-)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps.The key steps (Scheme 6) are the regio- and stereoselective photo<2+2>addition 7 -> 6 and the reductive fragmentation 6 -> 5.

Full text of DOI:10.1002/hlca.19830660213

Products guided by the article

Product name:3,3-dibutyl-6-methylcyclohexanone

Cas No:86678-47-9

R&D Labs maybe for 86678-47-9

NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307

Relevant to this article

Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids

Doi:10.1039/b925590g
(2010)
Crystal structure and spectroscopic characterization of Zinc(II) and mercury(II) complexes of N-(Pyridin-2-ylmethylene)benzene-1,4-diamine

Doi:10.1002/zaac.200801312
(2009)
Accurate O-H bond dissociation energy differences of hydroxylamines determined by EPR spectroscopy: Computational insight into stereoelectronic effects on BDEs and EPR spectral parameters

Doi:10.1021/jo1021794
(2011)
Chemoselective protection of α-Ketoacids by direct annulations with oximes

Doi:10.1021/ol100467t
(2010)
Palladium-Catalyzed Reactions in the Synthesis of 3- and 4-Substituted Indoles

Doi:10.1021/jo00278a029
(1989)
A facile route to ketene-functionalized polymers for general materials applications

Doi:10.1038/nchem.538
(2010)

Article Doi