45. Total Synthesis of (+/-)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage

DOI: 10.1002/hlca.19830660213

Source and publish data:

Helvetica Chimica Acta p. 522 - 533 (1983)

Update date:2022-09-26

Topics:

Authors:

Oppolzer, Wolfgang

Zutterman, Freddy

Baettig, Kurt

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19830660213

(+/-)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps.The key steps (Scheme 6) are the regio- and stereoselective photo<2+2>addition 7 -> 6 and the reductive fragmentation 6 -> 5.

Full text of DOI:10.1002/hlca.19830660213

Products guided by the article

Product name:3,3-dibutyl-6-methylcyclohexanone

Cas No:86678-47-9

R&D Labs maybe for 86678-47-9

Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone

Relevant to this article

Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids

Doi:10.1039/b925590g
(2010)
Crystal structure and spectroscopic characterization of Zinc(II) and mercury(II) complexes of N-(Pyridin-2-ylmethylene)benzene-1,4-diamine

Doi:10.1002/zaac.200801312
(2009)
Accurate O-H bond dissociation energy differences of hydroxylamines determined by EPR spectroscopy: Computational insight into stereoelectronic effects on BDEs and EPR spectral parameters

Doi:10.1021/jo1021794
(2011)
Chemoselective protection of α-Ketoacids by direct annulations with oximes

Doi:10.1021/ol100467t
(2010)
Palladium-Catalyzed Reactions in the Synthesis of 3- and 4-Substituted Indoles

Doi:10.1021/jo00278a029
(1989)
A facile route to ketene-functionalized polymers for general materials applications

Doi:10.1038/nchem.538
(2010)

Article Doi