Journal of Organic Chemistry p. 3308 - 3314 (1983)
Update date:2022-08-05
Topics:
Hoffman, Robert V.
Buntain, Gregory A.
The addition of p-nitrobenzenesulfonyl peroxide to 3,4-dihydro-2H-pyran (DHP) in alcohols gives high yields of 3-<<(p-nitrophenyl)sulfonyl>oxy>-2-alkoxytetrahydropyrans.The stereochemistry of the addition process is dependent on the steric bulk of the attacking alcohol.For small alcohols, trans addition predominates, while bulky alcohols give mostly cis product.The results are compared with analogous haloalkoxylations of DHP.
View MoreJiangsu Taihu New Materials Holding Co., Ltd
Contact:+86-519-86160108
Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Nanjing Zelang Medical Technology Co. Ltd
Contact:86-25-83063290/13770714480
Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
Wuhan Konberd Biotech Co., Ltd.
Contact:+86-27-87205925
Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Doi:10.1055/s-0034-1378784
(2015)Doi:10.1039/d1sc00450f
(2021)Doi:10.1021/jo051248f
(2005)Doi:10.1002/jccs.200400198
(2004)Doi:10.1021/jo051645q
(2005)Doi:10.1016/S0040-4039(00)81683-4
(1983)
