Journal of Organic Chemistry p. 3308 - 3314 (1983)
Update date:2022-08-05
Topics:
Hoffman, Robert V.
Buntain, Gregory A.
The addition of p-nitrobenzenesulfonyl peroxide to 3,4-dihydro-2H-pyran (DHP) in alcohols gives high yields of 3-<<(p-nitrophenyl)sulfonyl>oxy>-2-alkoxytetrahydropyrans.The stereochemistry of the addition process is dependent on the steric bulk of the attacking alcohol.For small alcohols, trans addition predominates, while bulky alcohols give mostly cis product.The results are compared with analogous haloalkoxylations of DHP.
View MoreShandong Topscience Biotech Co., Ltd.
Contact:0633-2619278
Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Shijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
website:http://www.trustwe.com
Contact:+86-21-61551413
Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Doi:10.1055/s-0034-1378784
(2015)Doi:10.1039/d1sc00450f
(2021)Doi:10.1021/jo051248f
(2005)Doi:10.1002/jccs.200400198
(2004)Doi:10.1021/jo051645q
(2005)Doi:10.1016/S0040-4039(00)81683-4
(1983)
