STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS. 45. CARBON-13 NMR STUDIES OF CARBOCATIONS. 9. VARIATION OF CATIONIC CARBON CHEMICAL SHIFTS WITH INCREASING ELECTRON DEMAND IN 1,1-DIARYL-1-ETHYL CARBOCATIONS. IMPORTANCE OF THE INDUCTIVE LOCALIZED pi -POLARIZATI

DOI: 10.1021/ja00358a019

Source and publish data:

Journal of the American Chemical Society p. 6300 - 6305 (1983)

Update date:2022-08-05

Topics:

Authors:

Brown Brown

Periasamy

Thirumalai

Kelly Kelly

Ciansiracusa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00358a019

Carbocations were prepared in either SbF//5/FSO//3H/SO//2ClF or FSO//3H/SO//2ClF solutions at minus 78 degree C and their **1**3C NMR spectra recorded at minus 70 degree C. The plots of the substituent chemical shifts DELTA delta C** plus against sigma **

Full text of DOI:10.1021/ja00358a019

Products guided by the article

Product name:Ethylium, 1-[3,5-bis(trifluoromethyl)phenyl]-1-(4-methylphenyl)-

Cas No:86767-00-2

R&D Labs maybe for 86767-00-2

HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,
Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China

Relevant to this article

Hydrophobic and electronic factors in the design of dialkylglycine decarboxylase mimics

Doi:10.1016/j.bmc.2005.05.019
(2005)
Reaction of ketenes with N,N-disubstituted α-aminomethyleneketones. XIII. Synthesis of 2H-pyrano[3,2-d]-1-benzoxepin derivatives

Doi:10.1002/jhet.5570200310
(1983)
Lewis basicity modulation of N-heterocycles: A key for successful cross-metathesis

Doi:10.1021/ol502016h
(2014)
F...H-N hydrogen bonding driven foldamers: Efficient receptors for dialkylammonium ions

Doi:10.1002/anie.200500982
(2005)
Novel C2-C3′ N-peptide linked macrocyclic taxoids. Part 1: Synthesis and biological activities of docetaxel analogues with a peptide side chain at C3′

Doi:10.1016/j.bmcl.2005.07.069
(2005)
A novel selective GABA_A α1 receptor agonist displaying sedative and anxiolytic-like properties in rodents

Doi:10.1021/jm058002n
(2005)

Article Doi