STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS. 45. CARBON-13 NMR STUDIES OF CARBOCATIONS. 9. VARIATION OF CATIONIC CARBON CHEMICAL SHIFTS WITH INCREASING ELECTRON DEMAND IN 1,1-DIARYL-1-ETHYL CARBOCATIONS. IMPORTANCE OF THE INDUCTIVE LOCALIZED pi -POLARIZATI

DOI: 10.1021/ja00358a019

Source and publish data:

Journal of the American Chemical Society p. 6300 - 6305 (1983)

Update date:2022-08-05

Topics:

Authors:

Brown Brown

Periasamy

Thirumalai

Kelly Kelly

Ciansiracusa

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Article abstract of DOI:10.1021/ja00358a019

Carbocations were prepared in either SbF//5/FSO//3H/SO//2ClF or FSO//3H/SO//2ClF solutions at minus 78 degree C and their **1**3C NMR spectra recorded at minus 70 degree C. The plots of the substituent chemical shifts DELTA delta C** plus against sigma **

Full text of DOI:10.1021/ja00358a019

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