Cyclization Reaction of Bis(tributylstannylated) α-Ketols with Heterocumulenes. Preparation of O,O-Vinylene Imino- and Thiocarbonates

DOI: 10.1246/bcsj.56.1873

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1873 - 1874 (1983)

Update date:2022-08-03

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Authors:

Sakai, Shizuyoshi

Murata, Masashi

Wada, Nobuto

Fujinami, Tatsuo

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Article abstract of DOI:10.1246/bcsj.56.1873

Aromatic α-ketols reacted with diethylaminotributylstannane at 60 deg C to afford a mixture of (Z)- and (E)-1,2-bis(tributylstannyloxy)-1,2-diarylethenes, which were allowed to react with organic isothiocyanates and carbon disulfide to give substituted O,

Full text of DOI:10.1246/bcsj.56.1873

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