Quassinoids. 2. Synthesis of an ABCD Ring Precursor Involving a Lactonization Induced by Iodotrimethylsilane

DOI: 10.1021/jo00167a017

Source and publish data:

Journal of Organic Chemistry p. 3242 - 3245 (1983)

Update date:2022-08-04

Topics:

Authors:

Voyle, Martyn

Dunlap, Norma K.

Watt, David S.

Anderson, Oren P.

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Article abstract of DOI:10.1021/jo00167a017

The Diels-Alder reaction of 3-formyl-4a,5,6,7,8,8aα-hexahydro-7β-(benzyloxy)-4aβ,8α-dimethylnaphthalen-2(1H)-one with 1-methoxy-3-(trimethylsilyloxy)-1,3-butadiene in benzene at 25 deg C furnished an extremely acid-labile Diels-Alder adduct, 3β-(benzyloxy

Full text of DOI:10.1021/jo00167a017

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