Carbanion-Accelerated Claisen Rearrangements. 2. Studies on Internal Asymmetric Induction

DOI: 10.1021/jo00167a058

Source and publish data:

Journal of Organic Chemistry p. 3369 - 3370 (1983)

Update date:2022-08-03

Topics:

Authors:

Denmark, Scott E.

Harmata, Michael A.

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Article abstract of DOI:10.1021/jo00167a058

The stereochemical course of Claisen rearrangements of 2 and 3 in the thermal and anionic modes has been studied.The carbanionic processes were shown to be highly stereoselective and dependent upon solent, counterion, and temperature.

Full text of DOI:10.1021/jo00167a058

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