Organometallics p. 1736 - 1742 (1983)
Update date:2022-08-03
Topics:
Grundy, Kevin R.
Robertson, Katherine N.
The platinum(I) dimers Pt2X2(μ-dppm)2 (X = Cl, I) react with p-tolyl isocyanide (CNR) under various conditions to give Pt2X2(μ-CNR)(μ-dppm)2, [Pt2X(CNR)(μ-dppm)2]+, [Pt2(CNR)2(μ-dppm)2]2+, and [Pt2(μ-CNR)(CNR)2(μ-dppm)2]2+. The complexes with bridging isocyanides undergo facile N-protonation and alkylation to yield the series of complexes [Pt2L2(μ-CNRR′)(μ-dppm)2] n+ (L = X, R′ = H, Me, n = 1; L = CNR, R′ = H, Me, n = 3). All structural assignments are made on the basis of vibrational, 1H NMR, and 31P NMR spectroscopy.
View MoreShanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Contact:+49-9398-993127
Address:Untertorstr. 27
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
SuZhou Hua-Emy Chemical Import and Export Co., LTD.
Contact:+86-512-88804994; +86-512-88804550;
Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
ChangZhou XiaQing Chemical Co., Ltd.
Contact:+86-519-88721665
Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Doi:10.1021/acscatal.1c02285
(2021)Doi:10.1063/1.459958
(1991)Doi:10.1021/ja074951p
(2007)Doi:10.1016/j.tetlet.2017.10.065
(2017)Doi:10.3390/ph12040161
(2019)Doi:10.1007/BF02220018
(1994)
