Journal of the Chemical Society, Dalton Transactions p. 447 - 452 (1989)
Update date:2022-09-26
Topics:
Al-Juaid, Salih S.
Eaborn, Colin
El-Kheli, Mohamed N. A.
Hitchcock, Peter R.
Lickiss, Paul D.
et al.
Tris(trimethylsilyl)methyl-lithium, LiC(SiMe3)3, reacts with trimethoxyborane to give the compound (Me3Si)3CB(OMe)2 (7) and the lithium-boron complex LiB(OMe)4 (8).The latter is converted on crystallisation from methanol into the solvate <(MeOH)2Li(μ-OMe)2 B(OMe)2> (11), which has been characterised by X-ray diffraction.The hydrolysis of (7) gives the dihydroxyborane (Me3Si)3CB(OH)2 (2), which may be converted into the dichloride (Me3Si)3CBCl2 (12), the difluoride (Me3Si)3CBF2 (14), the fluoride hydroxide (Me3Si)3CB(F)OH (15), the boranes(Me3Si)3CBR2
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