Combined 2H and 18O Isotop Effects in Support of a Concerted, Synchronous Elimination of Acetaldehyde from a Bis(benzyl ethyl ether) Radical Cation

DOI: 10.1021/ja00227a002

Source and publish data:

Journal of the American Chemical Society p. 6291 - 6297 (1988)

Update date:2022-08-04

Topics:

Authors:

Allison, Colin E.

Stringer, Michael B.

Bowie, John H.

Derrick, Peter J.

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Article abstract of DOI:10.1021/ja00227a002

No evidence has been found of "hydrogen scrambling" accompanying decomposition of the benzyl ether molecular ion at times approaching 100 μs.Isotope effects upon product ion abundances have been measured for elimination of acetaldehyde from the molecular

Full text of DOI:10.1021/ja00227a002

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