PREPARATION OF OPTICALLY ACTIVE PHOSPHINE OXIDES BY REGIOSELECTIVE CLEAVAGE OF CYCLIC PHENYLPHOSPHONITE WITH ALKYL HALIDES

DOI: 10.1246/cl.1983.913

Source and publish data:

Chemistry Letters p. 913 - 916 (1983)

Update date:2022-08-05

Topics:

Authors:

Segi, Masahito

Nakamura, Yoshiyuki

Nakajima, Tadashi

Suga, Sohei

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Article abstract of DOI:10.1246/cl.1983.913

The Arbuzov reaction of (2S,4S)-methyl-2-phenyl-1,3,2-dioxaphosphorinane with various alkyl halides gave the diastereomerically pure phosphinates with regioselective cleavage of the primary carbon-oxygen bond.These phosphinates reacted with Grignard reage

Full text of DOI:10.1246/cl.1983.913

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Product name:(2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane

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