PREPARATION OF OPTICALLY ACTIVE PHOSPHINE OXIDES BY REGIOSELECTIVE CLEAVAGE OF CYCLIC PHENYLPHOSPHONITE WITH ALKYL HALIDES

DOI: 10.1246/cl.1983.913

Source and publish data:

Chemistry Letters p. 913 - 916 (1983)

Update date:2022-08-05

Topics:

Authors:

Segi, Masahito

Nakamura, Yoshiyuki

Nakajima, Tadashi

Suga, Sohei

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.913

The Arbuzov reaction of (2S,4S)-methyl-2-phenyl-1,3,2-dioxaphosphorinane with various alkyl halides gave the diastereomerically pure phosphinates with regioselective cleavage of the primary carbon-oxygen bond.These phosphinates reacted with Grignard reage

Full text of DOI:10.1246/cl.1983.913

Products guided by the article

Product name:(2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane

Cas No:87248-70-2

R&D Labs maybe for 87248-70-2

shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
Suzhou Jingye Medicine & Chemical Co., Ltd

website:http://www.jingyechem.cn

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Shanghai Witshoot Internet Technology Co Ltd

Contact:+86-21-66390020

Address:Room 419, No.285 Luochuan Road (E)
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Doi:10.1080/07315724.2002.10719246
(1944)
Design and synthesis of 6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid derivatives as PPARγ activators

Doi:10.1016/j.bmcl.2007.05.081
(2007)
Discovery of Novel Small-Molecule Inhibitors of NF-κB Signaling with Antiinflammatory and Anticancer Properties

Doi:10.1021/acs.jmedchem.7b01557
(2018)
Synthesis of 2,5-dihydrobenzo[b]oxepins and 5,6-dihydro-2H-benzo[b]oxocines based on [3+3] cyclizations of 1,3-bis(silyl enol ethers)

Doi:10.1016/j.tet.2007.05.056
(2007)
Intramolecular cycloaddition of O-tert-butyldimethylsilyloximes in the presence of BF₃-OEt₂

Doi:10.1021/jo051652e
(2005)
Activated nitriles in heterocyclic synthesis. A novel synthesis of pyrazolo[1,5-a]pyrimidines and pyrano[2,3-c]pyrazoles

Doi:10.1002/jhet.5570200331
(1983)

Article Doi