Models of the Cytochromes b. 4. Effect of Axial Ligand Plane Orientation on the Proton NMR Spectra of Symmetrically Substituted Low-Spin Iron(III) Porphyrins

DOI: 10.1021/ja00361a030

Source and publish data:

Journal of the American Chemical Society p. 6923 - 6929 (1983)

Update date:2022-09-26

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Authors:

Walker, F. Ann

Buehler, Joanne

West, Joyce T.

Hinds, John L.

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Article abstract of DOI:10.1021/ja00361a030

Mixtures of the αβαβ and ααββ atropisomers of tetrakis(o-pivalamidophenyl)porphyrin, (o-piv)4TPPH2. were separated from the other atropisomers and the ratio determined by NMR techniques.Insertion of iron required extended reflux time, and significant (ca.

Full text of DOI:10.1021/ja00361a030

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