THE ACID INDUCED DECOMPOSITION OF 7-SUBSTITUTED 3-DIAZO-2-NORBORNANONES.THE STRUCTURES OF THE PRODUCTS AND THEIR DISTRIBUTION

DOI: 10.1016/S0040-4039(00)81942-5

Source and publish data:

Tetrahedron Letters p. 2419 - 2422 (1983)

Update date:2022-09-26

Topics:

Authors:

Yates, Peter

Kronis, John D.

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Article abstract of DOI:10.1016/S0040-4039(00)81942-5

Introduction of a syn-7 isopropyl or t-butyl substituent in 3-diazo-2-norbornanone results in both endo and exo protonation in aqueous acid and a marked decrease in α-ketol and increase in tricyclanone formation.

Full text of DOI:10.1016/S0040-4039(00)81942-5

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