Cp2TiCl2-catalyzed regio- and chemoselective one-step synthesis of γ-substituted allylsilanes from terminal alkenes using dianion-type zincate (SiSiNOL-Zn-ate)

DOI: 10.1021/ja0541074

Source and publish data:

Journal of the American Chemical Society p. 13116 - 13117 (2005)

Update date:2022-08-03

Topics:

Authors:

Nakamura, Shinji

Uchiyama, Masanobu

Ohwada, Tomohiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja0541074

A regio-/chemoselective silylation reaction of various functionalized terminal alkenes in the presence of titanocene dichloride, based on a newly designed dianion-type zincate, was developed. The present silylation of terminal alkenes is a powerful tool f

Full text of DOI:10.1021/ja0541074

Products guided by the article

Product name:((E)-Hept-2-enyl)-dimethyl-phenyl-silane

Cas No:87436-95-1

R&D Labs maybe for 87436-95-1

Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Weifang Jahwa Chemical Co.,Ltd

Contact:0086-536-8897731,8897730

Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences

Relevant to this article

Kinetic Analysis of the Rearrangement of a Conformationally Constrained α-Cyclopropylbenzyl Radical

Doi:10.1021/jo00092a003
(1994)
Asymmetric allylation/pauson-khand reaction: A simple entry to polycyclic amines. Application to the synthesis of aminosteroid analogues

Doi:10.1021/ol500142c
(2014)
Studies towards the synthesis of alkyl N-(4-nitrophenyl)-3/2-oxomorpholine- 2/3-carboxylates

Doi:10.1002/hlca.201300085
(2013)
Organotin-substituted organosiloxanes: synthesis and characterisation, including the crystal structure of 1,3-bis(triphenylstannoxy)-1,1,3,3-tetraphenyl-1,3-disiloxane

Doi:10.1016/0022-328X(94)87048-9
(1994)
Hydrolysis of aryl orthocarbonates by general acid catalyzed and spontaneous processes. Characterization of the water reaction of (ArO)₃COAr′ and (ArO)₃CN₃

Doi:10.1021/ja00092a009
(1994)
Antiulcer agents. III. Synthesis and antiulcer activity of N-[3-(3- piperidinomethylphenoxy)propyl]pentacyclo[4.2.0.0^2,5.0^3,8.0^4,7]- octane carboxamides and related compounds

Doi:10.1248/cpb.41.1760
(1993)

Article Doi