Organotin-substituted organosiloxanes: synthesis and characterisation, including the crystal structure of 1,3-bis(triphenylstannoxy)-1,1,3,3-tetraphenyl-1,3-disiloxane

DOI: 10.1016/0022-328X(94)87048-9

Source and publish data:

Journal of Organometallic Chemistry p. 145 - 152 (1994)

Update date:2022-08-03

Topics:

Authors:

Brisdon, B.J.

Mahon, M.F.

Molloy, K.C.

Schofield, P.J.

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Article abstract of DOI:10.1016/0022-328X(94)87048-9

A series of linear 1,3-bis(triorganostannoxy)siloxanes (R'3SnO)R2SiOSiR2(OSnR'3) (R=Me, Ph; R'=Ph, n-Bu, c-C6H11) has been synthesised, and the compounds characterised by NMR (1H, 13C, 29Si and 119Sn) and Moessbauer spectroscopies.The structure of the homoleptic compound R=R'=Ph has been determined by an X-ray diffraction study. Key words: Siloxanes; Stannoxy; Moessbauer spectroscopy; Crystal structure

Full text of DOI:10.1016/0022-328X(94)87048-9

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