
Journal of Organometallic Chemistry p. 145 - 152 (1994)
Update date:2022-08-03
Topics:
Brisdon, B.J.
Mahon, M.F.
Molloy, K.C.
Schofield, P.J.
A series of linear 1,3-bis(triorganostannoxy)siloxanes (R'3SnO)R2SiOSiR2(OSnR'3) (R=Me, Ph; R'=Ph, n-Bu, c-C6H11) has been synthesised, and the compounds characterised by NMR (1H, 13C, 29Si and 119Sn) and Moessbauer spectroscopies.The structure of the homoleptic compound R=R'=Ph has been determined by an X-ray diffraction study. Key words: Siloxanes; Stannoxy; Moessbauer spectroscopy; Crystal structure
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